Thanks. I assume the back up battery is re-chargeable, and gets it’s supply from the primary 12v car battery? So, if disconnected from the primary would, eventually, dissipate…but who knows how long that might take.…so probably not good solution to remove the fuse…just easier.
Yes, it's a rechargable one. If the charge status is low you get a ecall warning on the dash (I think the threshold is 40% based on a TSB I read a while ago). It recharges while driving, and will take a few hours. There should be no need to replace it even if it has drained completely.
In any case, the only situation I'm aware of that you need to disconnect it is if the keys aren't recognised and you want to power cycle the TCAM to fix this.
I suppose it's not impossible for the backup battery to also be completely flat, in which case merely disconnecting the 12V should do the trick to get the keys working, probably worth disconnecting 12V briefly and checking if the keys work before disconnecting 12V again and going ahead with the massive PITA of unplugging the back up battery.
There is no reason to replace the back up battery if it drained, it's similar to cell phone batteries so perfectly happy to discharge fully more than a few times. Volvo Assistance in the UK carry pre-charged ones and will swap them out when 12V has drained as that causes the TCAM to tap on that and drain it too very quickly, but the only reason they do that is to be able to clear all error messages before leaving the site. It wouldn't be good customer service to tell someone yeah you'll have an ecall warning error for the next 4-5 hours of driving and it's normal.